Transformation of hydrazinium azide to molecular N8 at 40 GPa
نویسندگان
چکیده
منابع مشابه
Molecular response of liquid nitrogen multiply shocked to 40 GPa.
Liquid nitrogen was subjected to multiple shock compression to examine its response to pressures (15-40 GPa) and temperatures (1800-4000 K) previously unexplored in static and shock compression studies. Raman spectroscopy measurements were used to characterize the molecular bond response and to determine temperatures in the peak state. By extending our analysis to include other Raman spectrosco...
متن کاملProton NMR Study of Molecular Dynamics in Hydrazinium Perchlorate
The proton spin-lattice relaxation time Tl (at 5.4, 10 and 15 MHz) and second moment M 2 (at 9.8 MHz) have been measured in hydrazinium Perchlorate (N 2 H 5 C10 4 ) . The temperature dependence of T, shows two minima. The low temperature T, minimum has been explained in terms of N H 3 reorientation about the N N axis while the high temperature minimum is attributed to the exchange of protons wi...
متن کامل3-Fluorosalicylaldoxime at 6.5 GPa
3-Fluoro-salicylaldoxime, C(7)H(6)FNO(2), unlike many salicylaldoxime derivatives, forms a crystal structure containing hydrogen-bonded chains rather than centrosymmetric hydrogen-bonded ring motifs. Each chain inter-acts with two chains above and two chains below via π-π stacking contacts [shortest centroid-centroid distance = 3.295 (1) Å]. This structure at 6.5 GPa represents the final point ...
متن کاملStructure of liquid iron at pressures up to 58 GPa.
We report structural data on liquid iron at pressures up to 58 GPa measured by x-ray scattering in a laser heated diamond anvil cell. The determined structure factor preserves essentially the same shape along the melting curve. Our data demonstrate that liquid iron at high pressures is a close-packed hard-sphere liquid. The results place important constraints on the thermodynamic and transport ...
متن کاملTHE EQUATION F STATE OF Mg 0 . 6 Fe 0 . 40 TO 200 GPa
Abstrac,t. New Hugoniot data on polycrystalline (avg.porosity 6.9%) samples of the magnesiowustite Mgo.6Fe0.40 are presented, covering the pressure range up to 200 GPa. When our data are fit by a single 3rd order Eulerian Hugoniot with K 0 constrained to its ultrasonic value of •61.5 GPa, the required isentropic pressure derivative K 0' is 4.37 +/0.37. This value is significantly lower than the...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: The Journal of Chemical Physics
سال: 2018
ISSN: 0021-9606,1089-7690
DOI: 10.1063/1.5021976